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Structure-Reactivity Correlations for Complex Formation Reactions between Square-Planar Metal Centers and Thioethers

SynopsisReactivity trends of thioethers toward square-planar complexes can be generally interpreted by use of an equation of the form: log k = γ + α∑σ* + βθ, where k denotes second-order rate constants, ∑σ* the sum of Taft constants for the thioether substituents, and θ the thioether cone angles. γ represents an intrinsic parameter for each substrate complex, while α is an electronic and β a steriSynopsisReactivity trends of thioethers toward square-planar complexes can be generally interpreted by use of an equation of the form: log k = γ + α∑σ* + βθ, where k denotes second-order rate constants, ∑σ* the sum of Taft constants for the thioether substituents, and θ the thioether cone angles. γ represents an intrinsic parameter for each substrate complex, while α is an electronic and β a steri

Motion control system of MAX IV Laboratory soft x-ray beamlines

At the MAX IV Laboratory, five new soft x-ray beamlines are under development. The first is Species and it will be used to develop and set the standard of the control system, which will be common across the facility. All motion axes at MAX IV will be motorized using stepper motors steered by the IcePAP motion controller and a mixture of absolute and incremental encoders following a predefined coor

Non-uniform fractional tessellation

We present a variation of fractional tessellation to provide more uniformly distributed tessellation in screen space. Tessellation weights are added at the vertices for added flexibility and we show that the quality is improved at a minor cost.

Resistivity monitoring for internal erosion detection at Hallby embankment dam

Internal erosion is one of the major reasons for embankment dam failures. Despite this, the knowledge of the temporal development of internal erosion in full scale structures is limited. Results from a research field monitoring program by daily resistivity measurements in Sweden clearly show long term changes in resistivity in the embankment dam. The results indicate that resistivity monitoring ca

A Relic In Spe: Theodoret’s Depiction of a Philosopher Saint

The following article is an interpretation of a narrative in Theodoret of Cyrrhus’ collective biography about the history of the monks of Syria, the Philotheos historia. The most well-known saint of Theodoret’s own diocese was James of Cyrrhestica. His biography has a central place in the PH, but has not received as much attention as that of his name- sake James of Nisibis, or Symeon the Stylite.

Mastering the integration chaos following frequent M&As: IS integration with SOA technology

The use of service oriented architectures (SOA) is rapidly penetrating contemporary business life based on the promise of scalable and flexible information infrastructures. However the technique is still in it infancy and many questions regarding the consequences of a shift towards this kind of IT architecture still remains unanswered. We approach the relation between SOA and another actual topic,

Heat loss from a thermal manikin during wet tests with walking simulation

The walking tests with a thermal manikin TORE were carried out with THERMPROTECT WP2 clothing. The test conditions simulated the human tests of the same work package, including ambient conditions (10 and 25 °C), clothing (impermeable and permeable), wetting of cotton underwear (wet and dry) and setting the walking speed to approximately the same level. Additional tests in homogenous conditions (Ta