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Natural Product Synthesis and Development of Novel Reaction Methodology

This thesis deals with the development of new reaction methodology for stereoselective synthesis, as well as total synthesis of natural products and investigations of the stereochemical outcome in the Mukaiyama aldol reaction. Chapter 2 describes efforts made towards the total synthesis of the oxindole natural products perophoramidine and the communesin. The first part of this chapter aims to de

A hygrothermal model to Simulate Moisture Conditions in Concrete Reactor Containments with Long-Term Temperature Gradients

Moisture plays a critical role in several degradation mechanisms affecting the structural components of nuclear power plants. It also significantly influences the long-term structural behaviour of reactor containments. This study presents a novel hygrothermal model that uses the relative humidity as the transport potential and accounts for the presence of a thermal gradient across the containment Moisture plays a critical role in several degradation mechanisms affecting the structural components of nuclear power plants. It also significantly influences the long-term structural behaviour of reactor containments. This study presents a novel hygrothermal model that uses the relative humidity as the transport potential and accounts for the presence of a thermal gradient across the containment