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Free energy perturbations have been performed on two blue copper proteins, plastocyanin and nitrite reductase. By changing the copper coordination geometry, force constants, and charges, we have estimated the maximum energy with which the proteins may distort the copper coordination sphere. By comparing this energy with the quantum chemical energy cost for the same perturbation on the isolated cop
The Rustenburg Layered Suite (RLS) of the Bushveld Complex in South Africa is the largest mafic–ultramafic-layered complex on Earth. The RLS is associated with marginal sills that penetrate into the ~2.2 billion-year-old sedimentary strata of the Pretoria Group. These sills are in contact and share some geochemical similarities with different zones of RLS and are classified in terms of chemical co
The Uitkomst Complex is considered to be coeval with, and genetically linked to the Rustenburg Layered Suite (RLS) of the Bushveld Large Igneous Province. This study reports new paleomagnetic, geochemical and geochronological results from the Uitkomst Complex and a crosscutting dyke at the Nkomati Mine. Primary magnetisations for the complex and the dyke are statistically indistinguishable. This,
High-volume, low-strength industrial wastewaters constitute a large potential for biogas production, which could be realized by membrane bioreactors operating at the ambient temperature of the wastewater. However, the start-up of low-temperature anaerobic processes using unadapted inoculum can be sensitive to overloading, which results in acidification. This study assessed if a novel acidification
In the wake of the economic and social crisis, Spanish fiction has looked for ways of reflecting (on) the political. One of the manners has been to attempt to understand how the crisis has affected subjectivity and, more concretely, how the subject navigates the society of the crisis. In this article, I study three recent novels—Alberto Olmos’ Ejército enemigo (2011), Bruno Galindo’s El público (2
We discuss how techniques from multiresolution analysis and phase space transforms can be exploited in solving a general class of evolution equations with limited smoothness. We have wave propagation in media of limited smoothness in mind. The frame that appears naturally in this context belongs to the family of frames of curvelets. The construction considered here implies a full-wave description
The Southern Ocean is split into several biogeographical provinces between convergence zones that separate watermasses of different temperatures. Recent molecular phylogenies have uncovered a strong phylogeographic structure among rockhopper penguin populations, Eudyptes chrysocome sensu lato, from different biogeographical provinces. These studies suggested a reclassification as three species in
We present a new implementation of the time-resolved fluorescence anisotropy technique for the analysis of carbon nanoparticles directly in a Bunsen-type propane flame. By exploiting femtosecond laser excitation, UV-visible laser-induced fluorescence and time resolution of the experimental set-up, small soot nanoparticles have been identified within the flame. From the measurement of the decay tim
The addition of a carbon nutrient feed to a fed-batch cultivation is often not enough to obtain satisfactory growth and/or production. In some cases, an additional feed with for example supplementary amino acids or complex media is required. This work presents the development of feeding strategies where more than one feed is required and the knowledge of the growth requirements is low. Simulations
Mirror therapy has been used as an alternative stimulus to feed the somatosensory cortex in an attempt to preserve hand cortical representation with better functional results.
ERP systems became popular with large organizations in the 1990s. In the 21st Century, these products were expanded by addition of supply chain management (SCM) and customer relationship management (CRM), as well as access through the Web, creating the ERP II concept. Efforts to increase the market led vendors to serve not only large organizations, but also focus more on small-to-medium sized ente
Lighting control systems have been traditionally employed to reduce energy use for lighting by, for example, maximizing daylight harvesting. When highly efficient light sources are installed and for tasks where maintaining target illuminance is particularly important, designers may decide to prioritize the latter together with energy use. In this context, the use of data-driven algorithms is emerg
This paper describes the diagnostic criteria for presbyvestibulopathy (PVP) by the Classification Committee of the Bárány Society. PVP is defined as a chronic vestibular syndrome characterized by unsteadiness, gait disturbance, and/or recurrent falls in the presence of mild bilateral vestibular deficits, with findings on laboratory tests that are between normal values and thresholds established fo
Predicted impacts of climate change on crops—including yield declines and loss of conservation lands—could be mitigated by exploiting existing diversity within crops. Here we examine this possibility for wine grapes. Across 1,100 planted varieties, wine grapes possess tremendous diversity in traits that affect responses to climate, such as phenology and drought tolerance. Yet little of this divers
This thesis collects contributions to wireline and wireless communication systems with an emphasis on multiuser and multicarrier physical layer technology. To deliver increased capacity, modern wireline access systems such as G.fast extend the signal bandwidth up from tens to hundreds of MHz. This ambitious development revealed a number of unforeseen hurdles such as the impact of impedance changes
Machine Learning (ML) applications shape, and are shaped by, human values. In the last decade classificatory models have become the most widely applied type of ML. However, since the invention of Generative Adverserial Networks (GANs) in 2014, the field of generative ML is likely to become equally prolific in the years to come. GANs can generate convincing fakes of video footage, pictures, graphic
IntroductionSelf efficacy (SE) relates to pupils' beliefs about their own capacities within a given field. It has been shown that an overestimation of one's own SE beliefs affects learning outcomes negatively. In the present study we examine SE beliefs in writing skills in two groups of secondary school pupils, one with hearing impairment, the other without.PurposeText writing is a complex skill,
