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Carbonyl exchange between [MX3(13CO)]–(MX = PdCl, PtCl or PtBr) and 12CO has been studied by IR and 13C NMR spectroscopies as a function of temperature. The exchange is first-order in both CO and complex concentration, and the activation entropies are negative, suggesting an associative reaction mechanism. There is a small solvent effect, but no chloride dependence. Activation parameters and rate Carbonyl exchange between [MX(3)((CO)-C-13)](-) (MX = PdCl, PtCl or PtBr) and (CO)-C-12 has been studied by IR and C-13 NMR spectroscopies as a function of temperature. The exchange is first-order in both CO and complex concentration, and the activation entropies are negative, suggesting an associative reaction mechanism. There is a small solvent effect. but no chloride dependence. Activation para

The rate constants for the chloride and bromide anations of Pd(H2O)42+, the chloride anations of PdCl3H2O−, the bromide anation of PdBr3H2O− and the acid hydrolysis of PdCl(H2O)3+, PdBr(H2O)3+, PdCl42−, and PdBr42− have been determined at 15, 25 and 35 °C using a stopped-flow technique. The ionic strength was 1.00 M and the supporting electrolyte perchloric acid. The obtained rate constants and th

The aim of this thesis is to explore the evolution of new technology-based firms (NTBFs) based on solid empirical material for the Swedish economy. NTBFs are argued to be one important type of entrepreneurial firms that contribute to technology change, knowledge spillovers, and economic growth. However, our knowledge concerning how NTBFs exert their technological and economic influences is far fro

The popularity of the Netflix series ‘Drive To Survive’ has almost doubled the amount of Formula 1 (F1) fans thanks to its great storytelling and compelling narratives about the drivers, teams, the rivalries between them and challenges they tackle. The first season aired in 2019 and it is estimated that more than 6.8 million people have watched the show. As a result, the F1 brand is stronger than

Current post-carbon transition trajectories are primarily based on a belief in technical solutions wherein considerations of the citizens’ role in collective mobilisation and transformation are largely overlooked. To this end, the thesis seeks to understand how citizens can become active agents of change within transition efforts and how their political agency can be empowered accordingly. This, b

The present paper is an analysis of Swedish law, as expressed obiter dictum in the Supreme Administrative Court decision of HFD 2012 ref. 20, regarding applicability of Swedish general anti avoidance rules in relation to tax treaty commitments. The purpose of the paper is to put Swedish law, as envisaged by HFD 2012 ref. 20, into an international perspective by drawing internationally relevant con

The kind of electoral system in use in a democracy affects voters possibilities regarding the number of parties/candidates any individual is allowed to support and if there is an opportunity to vote against parties/candidates that he or she does not want to see in power. In this study 235 Swedes were participated in a survey about how they experienced three different electoral systems regarding hoThe purpose of this study was to examine the relation between technostress, performance based self-esteem (PBS) and burnout among employees, further if technostress beyond PBS could act as a predictor for burnout. The participants in the study were white collar workers from a Swedish manufacturing industry who on a daily basis were using computer and information technology in their work. These com

Popular Abstract in Swedish Leukemi är en cancersjukdom i blod och benmärg som karakteriseras av en störd blodbildning. Vid normal blodbildning delar sig ett begränsat antal omogna blodceller så kallade blod stamceller (eller hematopoietiska stamceller) och mognar till funktionella blodceller. Genom att dela sig utan att mogna har stamcellerna även potential till at förnya sig själva. När nya stamAcute myeloid leukemia (AML) is a malignant disorder of the blood system. Hematopoietic stem cells (HSCs) supply and maintain this system by differentiating via intermediates into lineage-restricted progenitors that strongly proliferate to keep up with the high turn-over of mature blood cells. In AML, the mechanisms controlling differentiation and proliferation of myeloid cells are disturbed leadi

This anthropological study looks at theater improv as a social phenomena and how experienced theater improvisers explain the experience of theater improv when it is at its best. This study also relate theater improv to the anthropological tradition of performance research, the construction of narratives and navigation of self within the framework of the social structures of society. The study sho