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Iridium pincer complexes are among the most versatile catalysts for bond‑activation chemistry, yet their performance is often governed as much by off-cycle speciation and inhibition as by intrinsic reactivity. This thesis investigates how pincer ligand design influences the structure, dynamics, and catalytic behaviour of iridium complexes and their relevance to acceptorless dehydrogenation.Initial
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Bis(phosphinidene)-capped triiron carbonyl clusters, including electron rich derivatives formed by substitution with chelating diphosphines, have been prepared and examined as proton reduction catalysts. Treatment of the known cluster [Fe3(CO)9(µ3-PPh)2] (1) with various diphosphines in refluxing THF (for 5, refluxing toluene) afforded the new clusters [Fe3(CO)7(µ3-PPh)2(κ2-dppb)] (2), [Fe3(CO)7(µ
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In the study presented in this paper, a vehicle driving cycle simulation of the pneumatic hybrid has been conducted. The pneumatic hybrid powertrain has been modeled in GT-Power and validated against experimental data. The GT-Power engine model has been linked with a MATLAB/simulink vehicle model. The engine in question is a single-cylinder Scania D12 diesel engine, which has been converted to wor
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The longitudinal and multidisciplinary research project Malmö Youth Sport Study measured the sports results achieved by two cohorts of pupils using a variable named ACHIEVE, dividing the pupils into three categories (an elite group competing at the national or international level, a group competing at the district level, and a third group either not competing at all or below district level). This
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Registered- and community health nurses in municipal home care (hereafter referred to as home care nurses) have a demanding job that is special compared to other forms of healthcare. The work is mobile, and care in the field is often carried out in solitude. At the same time, the patients being cared for often have complex care needs, requiring cooperation and interaction. Contact with colleagues