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On the 9/21- level excitation energy of odd Tl, Au and Ir isotopes

A semi-empirical method inspired by Blomqvist's (1969) previous calculations of the excitation energy of the lowest 9/2- state of 201Tl is applied to similar calculations in different Tl, Au and Ir isotopes. These semi-empirical estimates agree well with the experimental values of the excitation energies as well as with the energy differences deduced from the analysis of the total potential energy

SPECT Imaging using Pinhole Collimation : System Design and Simulation Studies for Pre-Clinical and Clinical Imaging

Nuklearmedicinsk bildtagning med hjälp av radiofarmaka är ett viktigt verktyg för att studera biologiska processer och humansjukdomar. Bildtagning sker ofta med en detektor i kombination med en kollimator. En typ av kollimering är pinnhålskollimering, där ett pinnhål i ett opakt material placeras mellan en källa och en detektor. Pinnhålet fyller samma funktion som en optisk lins då emitterade fotoThe focus of this dissertation is the use of pinhole collimation in Nuclear Medicine. A pinhole is a single aperture in an opaque material that is placed between the detector and source of interest, and photons must pass through the hole to reach the detector. The choices of pinhole parameters, e.g. the pinhole material and size of the opening, are closely linked to the performance of the detector

Enrichment of dissolved silica in the deep equatorial Pacific during the Eocene-Oligocene

Silicon isotope ratios (expressed as δ30Si) in marine microfossils can provide insights into silica cycling over geologic time. Here we used δ30Si of sponge spicules and radiolarian tests from the Paleogene Equatorial Transect (Ocean Drilling Program Leg 199) spanning the Eocene and Oligocene (~50-23 Ma) to reconstruct dissolved silica (DSi) concentrations in deep waters and to examine upper ocean

Synthesis and characterization of FeIII(μ-OH)ZnII complexes : Effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a phosphate diester and DNA

The synthesis and characterization of three ligands and their respective heterobinuclear FeIIIZnII complexes were carried out, with the goal of mimicking the active site of purple acid phosphatases (PAPs). The ligand 2-hydroxy-3-(((2-hydroxy-5-methyl-3-(((2-(pyridin-2-yl)ethyl)(pyridin-2-ylmethyl)amino)methyl)benzyl)(pyridin-2ylmethyl)amino)methyl)-5-methylbenzaldehyde (H2L2) was synthesized and i

Classification of spectra of the Neumann–Poincaré operator on planar domains with corners by resonance

We study spectral properties of the Neumann–Poincaré operator on planar domains with corners with particular emphasis on existence of continuous spectrum and pure point spectrum. We show that the rate of resonance at continuous spectrum is different from that at eigenvalues, and then derive a method to distinguish continuous spectrum from eigenvalues. We perform computational experiments using the

Visible-Uv fluorescence studies of fragments resulting from the relaxation of molecular core hole states

The absorption of soft x-ray radiation induces neutral and ionic core hole states in molecules. The relaxation of such states typically leads to a multi-step process, at the end of which photons in the visible and UV range can also be emitted from fragments. In this paper, we present results on Balmer and Lyman emission that originates from excited H atoms produced at the K-edge of the water, ammo

Photocatalytic Degradation of Bacteriophages Evidenced by Atomic Force Microscopy

Methods to supply fresh water are becoming increasingly critical as the world population continues to grow. Small-diameter hazardous microbes such as viruses (20-100 nm diameter) can be filtered by size exclusion, but in this approach the filters are fouled. Thus, in our research, we are investigating an approach in which filters will be reusable. When exposed to ultraviolet (UV) illumination, tit

The Clinical Outcome of Hurler Syndrome after Stem Cell Transplantation

Hurler syndrome (HS) is a severe inborn error of metabolism causing progressive multi-system morbidity and death in early childhood. At present, stem cell transplantation (SCT) is the only available treatment that can prevent central nervous system disease progression in HS patients. Although SCT has been shown to be effective for several important clinical outcome parameters, the reported clinica

Serine, glycine, and threonine

Amino acids are not only indispensable for protein synthesis but also play important cellular functions. In this chapter, the central nervous system (CNS) functions of serine, glycine, and threonine are discussed. Both the specific functions of the aforementioned amino acids and the functions of their derivatives are reviewed in relation to brain development and neurotransmission. In particular, f

Land Use and Cover or Precipitation? : Changes on Hydrological Response of the Upper Paraná River Basin

The Upper Paraná River Basin (UPRB) has undergone extensive Land Use and Cover Changes (LUCC) in thelatest decades, due to rapid population growth and economic development. Furthermore, variation in precipitationpatterns was observed across the basin mainly after the 1970s Climate shift. Concurrently, the UPRB has presentedsignificant changes in its hydrology. In this context, this thesis investig

Time-resolved and steady-state fluorescence studies of hydrophobically modified water-soluble polymers

A comprehensive study of the photophysical behavior of poly(acrylic acids) randomly labeled with pyrene using steady-state and time-resolved fluorescence spectroscopy is presented. The influence of external factors, such as different solvents and pH in the aqueous solution, on the polymer photophysics has been investigated. These factors induce major changes in the polymer conformation, which are

Resources Reservation in a Reactive QoS Scheme

The user services assistant (USA) is a novel reactive QoS agent that provides facilities for managing user to user QoS in Internet environments. By being reactive, it overcomes the problems associated with QoS management schemes that have been proposed to date, such as the mapping of the QoS parameters to end system parameters, and pre-determining the optimum way of degrading/upgrading the QoS. Ho