Radiation induced topotactic [2+2] dimerisation of acrylate derivatives among the layers of a CaFe layered double hydroxide followed by IR spectroscopy
Various acrylates [E-phenylpropenoate, E-3(4'-nitrophenyl)propenoate, E-3(2',5'-difluorphenyl)propenoate, E-3(2'-thienyl)propenoate, E-3(4'-imidazolyl)propenoate or E-2,3-dimethylpropenoate] were successfully intercalated into Ca(II)Fe(III) layered double hydroxide (CaFe - LDH) verified by a range of instrumental methods. The possible arrangements for the organic anions were suggested on the basis
